Two of the game-week 31 fixtures have been postponed due to the final of the Copa del Rey coming also this weekend, which involved four of the Spanish Laliga teams.
Osasuna will host Elche at Estadio El Sadar to get the actions underway in the early kick-off game of the day.
Real Sociedad will lock horns with Sevilla in the other early kick-off game of the day on Sunday at Reale Seguros Stadium.
Atletico Madrid will confront Eibar in the afternoon kick-off game of the day at Estadio Wanda Metropolitano.
Deportivo Alaves will battle SD Huesca in the other afternoon fixture of the day at Estadio Mendizorroza.
Cadiz will face Celta Vigo in the evening kick-off game of the day at Estadio Ramon de Carranza.
Real Betis will welcome Valencia to Estadio Benito Villamarin in the other evening kick-off game of the day.
Getafe will host Real Madrid at Coliseum Alfonso Perez in the late kick-off game of the day on Saturday.
Levante will lock horns with Villarreal at Ciudad de Valencia in the other late kick-off game of the day on Sunday night.
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