Jose Arnaiz scored the opener in the 16th minute as he made it 1-0 to give Osasuna the lead.
Lionel Messi came close to getting the equaliser in the 22nd minute as his shot hit the crossbar from a direct free kick.
Lionel Messi was every where in the Osasuna's half trying to create chances at getting the equaliser but the visiting teams defence kept them at bay.
Martin Braithwaite went for goal in the 43rd minute but his shot trailed off wide as Barcelona couldn't get the equaliser.
Lionel Messi almost got their equaliser in the 54th minute but Sergio Herrera denied him with a great save.
Messi finally got the equaliser in the 62nd minute as he beautifully curved a direct free kick to make it level at 1-1.
Enric Gallego was sent off in the 85th minute for hitting Clement Lenglet with his elbow.
Roberto Torres scored in the 90+4 minute to give Osasuna the win at full time.
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