Luka Modric took a long range in the 16th minute at goal but Sergio Asenjo nicely saved the ball.
Karim Benzema broke the deadlock in the 29th minute to give the Los Blanco's a 1-0 lead with Luka providing the assist to that one.
Dani Carvajal came close to doubling the lead in the 54th minute but Sergio Asenjo denied him the opportunity to get the goal.
Benzema scored a brace to double Real Madrid's lead as he scored from the penalty spot in the 77th minute.
Victor Iborra pulled one back for Villarreal as he scored a header in the 83rd minute to make it 2-1.
Iborra missed a clear chance to get the equaliser in the 90+4 minute but his shot missed the target.
Marco Asensio tried to seal the match with a goal in the 90+5 minute but the goal is ruled out by VAR for offside.
Real Madrid won at full time with a 2-1 scoreline.
Barcelona loss to Osasuna means Real Madrid are La Liga champions for the 34th time.
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