5. LIVERPOOL VS CHELSEA FA Cup Tie
Liverpool goalkeeper Adrian gifted Willian Chelsea's opener after 13 minutes when he hopelessly fumbled his 20-yard shot, but the European champions had chances of their own only to see recalled keeper Kepa Arrizabalaga present a formidable barrier with a string of saves.
The game was effectively settled after 64 minutes when former Everton midfielder and Toffees fan Barkley surged from inside his own half on a solo run before beating Adrian with an emphatic strike.
4. ARSENAL VS LIVERPOOL
Sadio Mane looked to have set the champions on course for one of the three victories they needed to surpass Manchester City's record 100-point haul with the opener on 20 minutes at the Emirates.
But the bedrocks of Liverpool's title triumph handed Arsenal a half-time lead, as rare Van Dijk and Alisson mistakes were ruthlessly punished by Alexandre Lacazette and Reiss Nelson's first Premier League goal.
And, despite a commanding second-half performance, Liverpool were unable to prevent a third defeat of the season as Arsenal climbed to ninth after their first victory over Jurgen Klopp's side in five years.
3. WATFORD VS LIVERPOOL
Many had arrived at Vicarage Road expecting to see Liverpool make history by winning in the league for the 19th game in a row.
Indeed, such was the level of expectation that press accreditation for the game had been oversubscribed, with hundreds of media outlets keen to cover a moment in English football history.
But Watford were clearly not reading from the same script.
Ismaila Sarr scored twice while captain Troy Deeney added a third in a sparkling second-half display from the hosts as Liverpool's run of victories was brought to a shuddering halt.
The Reds had won their past 18 Premier League games and another at Vicarage Road would have made history as the longest winning run in the English top flight.
But they never got going against a Watford side who were superb from start to finish and who move out of the relegation zone as a result.
The Hornets had more chances in the first half and only a superb save from Alisson, to deny Troy Deeney, prevented them from leading at the break.
However, Watford deservedly went in front when Abdoulaye Doucoure squeezed a cross in from the left and the impressive Sarr was there to stab in.
Liverpool had fallen behind against West Ham last week but still managed to grind out a win. However, there was a feeling that this time was different, with the Reds sloppy in possession and lacking bite in attack.
It was no surprise that Watford doubled their advantage. Sarr was put through on goal by Will Hughes and the winger calmly lifted the ball over Alisson and into the net.
Captain Deeney then completed a famous victory, curling into the back of the net from the edge of the area.
This is not a result that is going to halt Liverpool's title charge with the Reds 22 points clear at the top but it was nevertheless an unexpected and memorable result for Watford.
2. MANCITY VS LIVERPOOL
A close contest was expected between the top two sides in England, but it turned into an absolute stroll for City and pointed to signs that they will aim to come back stronger next year.
De Bruyne pulled the strings and was unplayable at times with his array of passing, while Foden highlighted why he is a ready-made replacement for the departing David Silva with his intelligence both on and off the ball, contributing a goal and an assist.
The home side may be disappointed to have scored just the four in a dominant showing with Sterling seeing a shot deflected wide and Foden having a low strike cleared off the line by Virgil van Dijk.
Riyad Mahrez came off the bench and thought he had netted a fifth with a low drive at the near post, but the effort was ruled out by the video assistant referee for handball in the build-up.
Though they kept a clean sheet this time, City have struggled at the back by conceding 33 goals in 32 league games, and may well look to use the money from Leroy Sane's sale to Bayern to add a new centre-back.
Having already claimed the Carabao Cup and reached the semi-finals of the FA Cup while remaining in contention in the Champions League, City have plenty to look forward to from now until the end of the season and could well finish with another treble of trophies.
1. ATHLETICO MADRID VS LIVERPOOL
Jurgen Klopp's side - seeking to win the trophy for a seventh time - thought they had overturned Atletico's 1-0 advantage from the first leg when Roberto Firmino's first goal at Anfield this season at the start of the added 30 minutes gave them the lead in the tie.
Georginio Wijnaldum's first-half header was full reward for Liverpool laying siege to the Atletico goal for much of the first 90 minutes.
In the second half, Andrew Robertson was then inches away from a winner only for his header to crash against the woodwork.
And yet, as the Kop sensed another memorable Champions League victory, Adrian - deputising for the injured Alisson - paid the price for a dreadful clearance as substitute Marcos Llorente pounced with a low finish to secure Atletico's crucial away goal.
Llorente struck again with another composed finish in the 105th minute and with the spirit draining out of Liverpool and their supporters, former Chelsea striker Alvaro Morata adding insult to injury with a third in the dying seconds to send Atletico through to the last eight.
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